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Total surface of a finely divided solid per unit of mass

Scratches, represented by triangular-shaped grooves, make the surface area greater.

Specific 2️⃣ surface area (SSA) is a property of solids defined as the total surface area (SA) of a material per unit 2️⃣ mass,[1] (with units of m2/kg or m2/g). Alternatively, it may be defined as SA per solid or bulk volume[2][3] (units 2️⃣ of m2/m3 or m−1).

It is a physical value that can be used to determine the type and properties of a 2️⃣ material (e.g. soil or snow). It has a particular importance for adsorption, heterogeneous catalysis, and reactions on surfaces.

Measurement [ edit 2️⃣ ]

...and plastic Białecki rings of increased SSA

Values obtained for specific surface area depend on the method of measurement. In adsorption 2️⃣ based methods, the size of the adsorbate molecule (the probe molecule), the exposed crystallographic planes at the surface and measurement 2️⃣ temperature all affect the obtained specific surface area.[4] For this reason, in addition to the most commonly used Brunauer–Emmett–Teller (N 2️⃣ 2 -BET) adsorption method, several techniques have been developed to measure the specific surface area of particulate materials at ambient 2️⃣ temperatures and at controllable scales, including methylene blue (MB) staining, ethylene glycol monoethyl ether (EGME) adsorption,[5] electrokinetic analysis of complex-ion 2️⃣ adsorption[4] and a Protein Retention (PR) method.[6] A number of international standards exist for the measurement of specific surface area, 2️⃣ including ISO standard 9277.[7]

Calculation [ edit ]

The SSA can be simply calculated from a particle size distribution, making some assumption 2️⃣ about the particle shape. This method, however, fails to account for surface associated with the surface texture of the particles.

Adsorption 2️⃣ [ edit ]

The SSA can be measured by adsorption using the BET isotherm. This has the advantage of measuring the 2️⃣ surface of fine structures and deep texture on the particles. However, the results can differ markedly depending on the substance 2️⃣ adsorbed. The BET theory has inherent limitations but has the advantage to be simple and to yield adequate relative answers 2️⃣ when the solids are chemically similar. In relatively rare cases, more complicated models based on thermodynamic approaches, or even quantum 2️⃣ chemistry, may be applied to improve the consistency of the results, but at the cost of much more complex calculations 2️⃣ requiring advanced knowledge and a good understanding from the operator.[8]

Gas permeability [ edit ]

This depends upon a relationship between the 2️⃣ specific surface area and the resistance to gas-flow of a porous bed of powder. The method is simple and quick, 2️⃣ and yields a result that often correlates well with the chemical reactivity of a powder. However, it fails to measure 2️⃣ much of the deep surface texture.

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